Refrigerant Knowledge Center

What Is R404A Refrigerant? Properties, Uses and Safety

R404A is an A1 HFC blend long used in low- and medium-temperature refrigeration, but its very high GWP has made lower-GWP retrofit and new-equipment options central to system planning.

DesignationR404A
FamilyHFC blend
Safety ClassA1
GWP3922
ODP0
Lifecyclephase-down

What Is R404A?

R404A is an A1 HFC blend long used in low- and medium-temperature refrigeration, but its very high GWP has made lower-GWP retrofit and new-equipment options central to system planning.

R404A is classified as near-azeotropic blend in the HFC blend family. Its composition is 52% R143a / 44% R125 / 4% R134a by mass. Refrigerant choice is never based on designation alone: capacity, pressure, lubricant, controls, heat-exchanger behavior, safety standards and local rules all matter.

R404A Technical Properties

General reference values for comparison; a current product specification and applicable regulatory basis govern a transaction.

Refrigerant designation R404A
Chemical family HFC blend
Composition 52% R143a / 44% R125 / 4% R134a by mass
Blend type near-azeotropic blend
ASHRAE safety class A1
100-year GWP 3922 (IPCC AR4 100-year)
Ozone depletion potential 0
Normal boiling reference -46.2 to -45.5 °C
GWP basis matters: different IPCC assessment reports can assign different values to the same refrigerant. Use the value specified by the regulation or procurement standard that applies to your project.

Common R404A Applications

Typical references include low- and medium-temperature commercial refrigeration, and transport refrigeration.

Low- And Medium-temperature Commercial Refrigeration

Use depends on equipment design, operating envelope and applicable local requirements.

Transport Refrigeration

Use depends on equipment design, operating envelope and applicable local requirements.

Advantages and Limitations

Selection advantages

  • Established refrigerant designation with published reference data.
  • Application history in low- and medium-temperature commercial refrigeration.
  • ODP reference of 0.

Important limitations

  • A1 safety controls must be applied.
  • GWP and lifecycle status can affect long-term selection.
  • No refrigerant should be treated as a universal drop-in.

Environmental Impact and Regulation

Use and servicing are restricted in several markets because of high GWP; always check the exact end-use and reclaimed-gas provisions.

R404A has an ODP reference of 0 and a stated GWP of 3922 using IPCC AR4 100-year. Regulations commonly distinguish between manufacturing or import, new equipment, servicing, recovered material and individual end uses.

Verification date: July 2026. Confirm current rules with the competent authority for the destination and equipment category before making a compliance decision.

Safety, Handling and Storage

Charge the blend as liquid and follow the equipment and compressor manufacturers’ retrofit guidance; selection of an alternative is system specific.

The A1 classification describes toxicity and flammability groupings; it does not by itself approve a refrigerant for a particular system. Review the current safety data sheet, cylinder label, transport classification, equipment manual and local code.

R404A Alternatives and Comparisons

Candidate alternatives must be evaluated as system choices, not simple chemical substitutions.

R448A

HFO/HFC blend; A1 safety class; GWP 1273 on the stated IPCC AR5 100-year, manufacturer-reported basis.

Read the R448A guide

R449A

HFO/HFC blend; A1 safety class; GWP 1282 on the stated IPCC AR5 100-year, manufacturer-reported basis.

Read the R449A guide

R454C

HFO/HFC blend; A2L safety class; GWP 146 on the stated IPCC AR5 100-year, manufacturer-reported basis.

Read the R454C guide

R290

hydrocarbon; A3 safety class; GWP 3 on the stated IPCC AR4 100-year basis.

Read the R290 guide

R744

natural refrigerant; A1 safety class; GWP 1 on the stated CO2 reference value, 100-year basis.

Read the R744 guide

Need a commercial quotation?

Review packaging, documentation and inquiry requirements for R404A.

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R404A Frequently Asked Questions

What is R404A made of?

52% R143a / 44% R125 / 4% R134a by mass; it is categorized as near-azeotropic blend.

What is the safety class of R404A?

The published classification used in this guide is A1. Equipment approval and local safety rules still apply.

What is the GWP of R404A?

The reference here is 3922 on the IPCC AR4 100-year basis. Other assessment bases may show a different number.

Can R404A replace another refrigerant directly?

No universal drop-in claim is made. Compatibility and conversion requirements must be confirmed for the exact equipment.

Where is R404A commonly used?

Typical applications include low- and medium-temperature commercial refrigeration, and transport refrigeration, subject to equipment design and local approval.

References and Technical Sources

Source data is summarized for general education. Always use current official documents, standards and supplier-specific safety and technical data for engineering or compliance decisions.

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